Synthesis, Crystal Structure and Computational Studies of 1-Phenylpiperazin-1,4-Diium Nitrate Monohydrate
نویسندگان
چکیده
منابع مشابه
1-Benzylpiperazine-1,4-diium bis(perchlorate) monohydrate
In the title compound, C(11)H(18)N(2) (2+)·2ClO(4) (-)·H(2)O, one perchlor-ate anion is disordered over two orientations in a 0.66 (3):0.34 (3) ratio. Inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds link the cations, anions and water mol-ecules into ribbons extending along [100].
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The reaction of [PPhJ, NOS,] with CuCl and KSCN (1 :3:3) in acetone produces the yell-ow crystals of [PPh,], [WOS,(CuNCS),]. The crystals are triclinic, space group P1(2), z=2, a=12.4823(7), b=12.9224(7), c=18.6395(10)?, ?=83.907(5), ?= 73.152(4), Y= 65.194(4)'. The crystal structure was determined by single crystal Xray diffraction methods (Mo-K ?) and refined by least-squares calculations ...
متن کاملSynthesis and Crystal Structure of Copper(I) Nitrate π-complex with 1-allylbenzotriazole of Equimolar Composition.
The CuNO3 • C6H4N3(C3H5) compound (I) was obtained by alternating current electrochemical synthesis, starting from an ethanol solution containing Cu(NO3)2 • 3H2O and a mixture of 1- and 2-allylbenzotriazole titrated by HNO3 to pH = 4. The C=C bond of one 1-allylbenzotriazole molecule, the nitrogen atom from another ligand moiety, and two oxygen atoms from two nitrate-anions form a trigonal-pyra...
متن کامل1-(4-Chlorophenyl)piperazine-1,4-diium tetrachloridozincate(II) monohydrate
In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol-ecules and the 1-(4-chloro-phen-yl)piperazine-1,4-diium cations inter-act with the [ZnCl(4)](2-) anions through O-H⋯Cl, N-H⋯Cl, N-H⋯O and C-H⋯Cl hydrogen bonds (five simple and one bifurcated). Inter-molecular π-π stacking inter-...
متن کاملCrystal structure of 1-methylimidazole 3-oxide monohydrate
1-Methylimidazole 3-N-oxide (NMI-O) crystallizes as a monohydrate, C4H6N2O·H2O, in the monoclinic space group P21 with Z' = 2 (mol-ecules A and B). The imidazole rings display a planar geometry (r.m.s. deviations = 0.0008 and 0.0002 Å) and are linked in the crystal structure into infinite zigzag strands of ⋯NMI-O(A)⋯OH2⋯NMI-O(B)⋯OH2⋯ units by O-H⋯O hydrogen bonds. These chains propagate along t...
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ژورنال
عنوان ژورنال: E-Journal of Chemistry
سال: 2012
ISSN: 0973-4945,2090-9810
DOI: 10.1155/2012/826348